Latest press release has the Big East TV appearances. They grouped them by networks so here are the relevant (Pitt) appearances.

ABC
Fri., Nov. 28 WEST VIRGINIA at PITTSBURGH Noon

ESPN
Thurs., Oct. 2 PITTSBURGH at USF 7:30 p.m.
Sat., Dec. 6 PITTSBURGH at CONNECTICUT * TBD (might air on ESPN2)

ESPNU
Sat., Aug. 30 Bowling Green at Pittsburgh Noon

CBS College Sports
Sat., Oct. 18 Pittsburgh at Navy 3:30 p.m.

NBC
Sat., Nov. 1 Pittsburgh at Notre Dame 2:30 p.m.

ESPN Regional/Big East Game of the Week
Sat., Nov. 22 PITTSBURGH at CINCINNATI or WEST VIRGINIA at LOUISVILLE

ESPN Regional
Sat., Sept. 6 Buffalo at Pittsburgh 6 p.m.
SportsNet New York/ESPN GamePlan

CBS College Sports is what used to be the  CSTV channel. They rebranded it during the NCAA Tournament and after CBS purchased them outright.

More games will be added, but this is what is known so far. For example the October 25 BE Game of the week is open — and just happens to be the day Rutgers-Pitt play. So that will likely get added.

Not bad for Pitt to already have 6 games on national (non-PPV/regional) distribution considering the last few years. As for the other schools: Louisville has 6 games, WVU has 5 games, USF has 5, UConn has 5, Rutgers has 4, Cinci has 4, Syracuse has 3